Producción Científica Profesorado

Electrochemical Determination of Pb(II) Using Carbon Paste Electrodes Modified with Ion Imprinted Polymers (IIPs).



Galan Vidal, Carlos Andres

2022

Luz E. Rebolledo, Giaan Arturo Álvarez Romero, Israel Samuel Ibarra-Ortega, Carlos Andres Galan-Vidal, Irma Pérez-Silva. (2022). Electrochemical Determination of Pb(II) Using Carbon Paste Electrodes Modified with Ion Imprinted Polymers (IIPs). ECS Transactions, 106, 21.


Abstract


An easy, low-cost, and highly selective carbon paste electrode based on an ion-imprinted polymer (IIP) to determine Pb(II) in real samples was developed. The recognition cavities based on a cross-linked polymer selective to Pb(II) were created using vinyl pyridine. The modified CPE was constructed by a composite mixture with the synthesized IIP. A notable difference was observed in the electrochemical response of the electrodes modified with the IIP and a non-imprinted polymer, demonstrating the unique properties of the IIP recognition sites. The parameters related to the current intensity were optimized; the selectivity was also studied considering potential interference ions. The proposed modified electrode demonstrated to be as (or more) selective to Pb(II) compared to others previously reported in the literature. A linear concentration range from 3.3 mg/L to 33 mg/L with a limit detection of 1 mg/L was obtained. The Pb(II) preconcentrated on the electrode surface was successfully quantified in real potable water samples without previous treatment.






Artículos relacionados

Cobalt electrodeposition onto highly oriented pyrolytic graphite (HOPG) electrode from ammonium sulf...

Predicting the Phase Diagram of a Liquid Crystal Using the Convex Peg Model and the Semiempirical PM...

A Voltammetric Study Of The Underpotential Deposition Of Cobalt Onto A Glassy Carbon Electrode

THEORETICAL STUDY ON THE MODIFICATION OF ACTIVE SITES IN GOLD SURFACES MODELED AS FINITE CLUSTERS: I...

Hydrogen bond studies in substituted N-(2-hydroxyphenyl)--2-[(4-methylbenzenesulfonyl)amino]acetamid...

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane

Synthesis of Zn compounds derived from 1H-benzimidazol-2-ylmethanamine

Estudio de las Interacciones Ácido Húmico-Metales Pesados y Determinación de sus Constantes de Estab...

Underpotential deposition of cobalt onto polycrystalline platinum