Expedient synthesis of highly functionalized abnormal gold complexes.
Alvarez Hernandez, Alejandro
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes
Furocoumarins of three species of the genus Dorstenia
Structural studies of spiroarsoranes derived from 2-aminophenols
Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles
Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters
Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles