Producción Científica Profesorado

Expedient synthesis of highly functionalized abnormal gold complexes.



Mendoza Espinosa, Daniel

2018

Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.


Abstract


The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups






Artículos relacionados

Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor

Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling

Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives

Regioselective Synthesis of 3-Indolyl(alkoxy)acetates

Synthesis of Acetamido(indol-3-yl)propanol Derivatives

13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters

Preparation of 3-hydroxyoxindoles with dimethyldioxirane and their use for the synthesis of natural ...

Role of lipid peroxidation in biliary obstruction in the rat

Reactivity of TpMe2Ir(C2H4)(DMAD) with carboxylic acids. A DFT study on geometrical isomers and stru...

Synthesis of Indolylindolines Mediated by tert-BuNH2