Expedient synthesis of highly functionalized abnormal gold complexes.
Mendoza Espinosa, Daniel
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea
First Total Synthesis of ()-Flustraminol B
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2
Transesterifications mediated by t-BuNH2
The absoluteconfiguration of cuauhtemone and related compounds
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase