Producción Científica Profesorado

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexes with a C4 Symmetric Tetratriazol-5-ylidene



González Montiel, Simplicio

2017

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexeswith a C4?Symmetric Tetratriazol-5-ylideneMariana Flores-Jarillo, Daniel Mendoza-Espinosa,* Verónica Salazar-Pereda, Simplicio González-Montiel, Organometallics, 2017doi:10.1021/acs.organomet.7b00712


Abstract


The facile preparation of a C4-symmteric tetratriazolium salt and its subsequent metalation to generate a series of tetranuclear mesoionic carbene gold(I) complexes is presented. The complete structural characterization of the metallic carbenes and the benefits of cooperative catalysis in the processes of hydroamination and hydrohydrazination of terminal alkynes are discussed.



Producto de Investigación



Artículos relacionados

Synthesis, characterization and crystal structures of dipyridyl-N-methylimine and cloro-bis (N,N?-2,...

Organometallic tin complexes derived from 2-guanidinobenzimidazole

Five-membered ring chelate complexes of Ni(II), Pd(II) and Pt(II) derived of di-(2-pyridyl)-N-ethyli...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Six-membered ring chelate complexes of Pd(II) and Pt(II) derived from di-(2-pyridyl)pyrimidin-2-ylsu...

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Understanding and Predicting Distorted T- versus Y-Geometries for Neutral Chromous Complexes Support...

Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying...

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...