Facile synthesis and structural characterization of 4-oxo tetrazinc clusters of beyerenoic and kaurenoic acids
Alvarado Rodríguez, José Guadalupe
2017
Mario A. Gómez-Hurtado, Karina Nava-Andrade, Ana K. Villagómez-Guzmán, Rosa E. del Río, Noemí Andrade-López, José G. Alvarado-Rodríguez, Diego Martínez-Otero, David Morales-Morales, Gabriela Rodríguez-García, Tetrahedron Letters, 2017, 58(12) 1112-1116.https://doi.org/10.1016/j.tetlet.2017.01.085
Abstract
The naturally occurring diterpenoids beyerenoic (1) and kaurenoic acids (2) extracted from Perymenium buphthalmoides DC., were treated with NaOH and reacted with ZnCl2 to afford two ?4-Oxo tetrazinc clusters (?4-oxo)-hexakis(?2-beyerenate)-tetra-zinc(II) (5) and (?4-oxo)-hexakis(?2-kaurenate)-tetra-zinc(II) (6). Both species were unequivocally characterized and their structures in the solid state determined by single crystal X-ray diffraction techniques.
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