Synthesis of Fluorescent oligo(p-phenyleneethynylene) (OPE3)via Sonogashira Reactions
Suárez Castillo, Oscar Rodolfo
2015
Mariana Flores-Jarillo, Francisco Ayala-Mata, Gerardo Zepeda-Vallejo, Rosa Ángeles Vázquez-García, Gabriel Ramos-Ortiz, Miguel Ángel Méndez-Rojas, Oscar Rodolfo Suárez-Castillo, and AlejandroAlvarez-Hernández, Synthesis of Fluorescent oligo(p-phenyleneethynylene) (OPE3)via Sonogashira Reactions, J. Mex. Chem. Soc. 2015, 59(2), 151-160.
Abstract
Sonogashira reactions of 4-(2,5-diiodobenzoyl)morpholine and 4-(5-bromo-2-iodobenzoyl)morpholine with arylacetylenes catalyzed by Pd2(dba)3 in DMSO allowed preparation of fluorescent oligo(p-phenyleneethynylene)s (OPE3) with fluorescence quantum yields up to 0.87. DMSO proved to be very efficient for this double Sonogashira coupling in which other solvents failed.
Artículos relacionados
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea
Synthesis of Indolylindolines Mediated by tert-BuNH2
Transesterifications mediated by t-BuNH2
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2
One-potsynthesis of conformationallyrestrictedspirooxindoles
First Total Synthesis of ()-Flustraminol B
Role of lipid peroxidation in biliary obstruction in the rat