Synthesis of Fluorescent oligo(p-phenyleneethynylene) (OPE3)via Sonogashira Reactions
Alvarez Hernandez, Alejandro
2015
Mariana Flores-Jarillo, Francisco Ayala-Mata, Gerardo Zepeda-Vallejo, Rosa Ángeles Vázquez-García, Gabriel Ramos-Ortiz, Miguel Ángel Méndez-Rojas, Oscar Rodolfo Suárez-Castillo, and AlejandroAlvarez-Hernández, Synthesis of Fluorescent oligo(p-phenyleneethynylene) (OPE3)via Sonogashira Reactions, J. Mex. Chem. Soc. 2015, 59(2), 151-160.
Abstract
Sonogashira reactions of 4-(2,5-diiodobenzoyl)morpholine and 4-(5-bromo-2-iodobenzoyl)morpholine with arylacetylenes catalyzed by Pd2(dba)3 in DMSO allowed preparation of fluorescent oligo(p-phenyleneethynylene)s (OPE3) with fluorescence quantum yields up to 0.87. DMSO proved to be very efficient for this double Sonogashira coupling in which other solvents failed.
Artículos relacionados
Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.
Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.
O-benzyl-N-(2-furoyl)thiocarbamate
The Structural Chemistry of N-Monolithium Borazines
Structural studies of spiroarsoranes derived from 2-aminophenols
Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes