Producción Científica Profesorado

Quantification of As(III) by Swasv on Glassy Carbon Electrode Codeposit Copper with Presence of B-Ciclodextrin



Mendoza Huizar, Luis Humberto

2013

López-Vargas, E., Galán-Vidal, C.A., Rodríguez-Ávila, J.A., Álvarez-Romero, G.A. Mendoza-Huizar, L.H. ECS Trans.. 2013, 47(1), 131-136.


Abstract


Nowadays, the ability to detect arsenic in drinking water is a very important subject because of arsenic's toxicity. In this sense, it is necessary to have economical and portable detection methodologies in order to control water quality, mainly in remote communities without access to expensive equipment such as atomic absorption. Currently, electrochemical methods are a low cost alternative which can be used outside the laboratory; however, these techniques use toxic or precious metals as working electrodes. The main interference in the quantification of arsenic is the Cu(II) because an intermetallic compound is formed with arsenic. In this paper we explore the co-deposition of Cu on a glassy carbon electrode to quantify As(III) in H2SO4 as a supporting electrolyte. The methodology reported a detection limit of 5.2 ?g L-1, helpful to following the official guidelines. Zn2+, Fe2+, Pb2+, Hg2+ and Cl- are not significant interferences in quantification.



Producto de Investigación




Artículos relacionados

Magnetic transition phase diagram of cobalt clusters electrodeposited on HOPG: Experimental and micr...

THEORETICAL STUDY ON THE MODIFICATION OF ACTIVE SITES IN GOLD SURFACES MODELED AS FINITE CLUSTERS: I...

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?

Análisis del Comportamiento Presión-Temperatura en la Transición Isotrópico-Nemático del p-Azoxianis...

Nucleation and growth of cobalt onto different substrates: Part II. The upd-opd transition onto a go...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing di...

Quantum chemical study of the electrochemical reduction of the [Co(H2O)6]2+ and [Co(NH3)5(H2O)]2+ io...

ELECTROCHEMICAL STUDY ABOUT ZINC ELECTRODEPOSITION ONTO GCE AND HOPG SUBSTRATES

Electrochemical kinetic study about cobalt electrodeposition onto GCE and HOPG substrates from sulfa...

Copper Electrodeposition On Glassy Carbon And Highly Oriented Pyrolytic Graphite Substrates From Per...