Producción Científica Profesorado

Quantification of As(III) by Swasv on Glassy Carbon Electrode Codeposit Copper with Presence of B-Ciclodextrin



Mendoza Huizar, Luis Humberto

2013

López-Vargas, E., Galán-Vidal, C.A., Rodríguez-Ávila, J.A., Álvarez-Romero, G.A. Mendoza-Huizar, L.H. ECS Trans.. 2013, 47(1), 131-136.


Abstract


Nowadays, the ability to detect arsenic in drinking water is a very important subject because of arsenic's toxicity. In this sense, it is necessary to have economical and portable detection methodologies in order to control water quality, mainly in remote communities without access to expensive equipment such as atomic absorption. Currently, electrochemical methods are a low cost alternative which can be used outside the laboratory; however, these techniques use toxic or precious metals as working electrodes. The main interference in the quantification of arsenic is the Cu(II) because an intermetallic compound is formed with arsenic. In this paper we explore the co-deposition of Cu on a glassy carbon electrode to quantify As(III) in H2SO4 as a supporting electrolyte. The methodology reported a detection limit of 5.2 ?g L-1, helpful to following the official guidelines. Zn2+, Fe2+, Pb2+, Hg2+ and Cl- are not significant interferences in quantification.



Producto de Investigación




Artículos relacionados

Chemical Reactivity of Atrazine Employing the Fukui Function

A theoretical quantum study on the distribution of electrophilic and nucleophilic active sites on Ag...

ELECTROCHEMICAL STUDY ABOUT ZINC ELECTRODEPOSITION ONTO GCE AND HOPG SUBSTRATES

Quantum chemical study of the electrochemical reduction of the [Co(H2O)6]2+ and [Co(NH3)5(H2O)]2+ io...

A theoretical quantum study on the distribution of electrophilic and nucleophilic active sites on th...

Efecto de la composición del soporte sobre las estructuras superficiales de óxidos de níquel y molib...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing di...

The role of temperature in copper electrocrystallization in ammoniachloride solutions

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Kinetic study of the cobalt electrodeposition onto glassy carbon electrode from ammonium sulfate sol...