Producción Científica Profesorado

Quantification of As(III) by Swasv on Glassy Carbon Electrode Codeposit Copper with Presence of B-Ciclodextrin



Mendoza Huizar, Luis Humberto

2013

López-Vargas, E., Galán-Vidal, C.A., Rodríguez-Ávila, J.A., Álvarez-Romero, G.A. Mendoza-Huizar, L.H. ECS Trans.. 2013, 47(1), 131-136.


Abstract


Nowadays, the ability to detect arsenic in drinking water is a very important subject because of arsenic's toxicity. In this sense, it is necessary to have economical and portable detection methodologies in order to control water quality, mainly in remote communities without access to expensive equipment such as atomic absorption. Currently, electrochemical methods are a low cost alternative which can be used outside the laboratory; however, these techniques use toxic or precious metals as working electrodes. The main interference in the quantification of arsenic is the Cu(II) because an intermetallic compound is formed with arsenic. In this paper we explore the co-deposition of Cu on a glassy carbon electrode to quantify As(III) in H2SO4 as a supporting electrolyte. The methodology reported a detection limit of 5.2 ?g L-1, helpful to following the official guidelines. Zn2+, Fe2+, Pb2+, Hg2+ and Cl- are not significant interferences in quantification.



Producto de Investigación




Artículos relacionados

Potentiometric behavior of graphite-epoxy electrochemical transducers towards anions, cations and pH...

THEORETICAL STUDY ON THE MODIFICATION OF ACTIVE SITES IN GOLD SURFACES MODELED AS FINITE CLUSTERS: I...

Zinc Electrodeposition from Chloride Solutions onto Glassy Carbon Electrode

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Synthesis, Characterization and Catalytic Activity of Supported NiMo Catalysts

Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane

Cobalt Electrodeposition Process from Electrolytic Baths based on CoSO4 and (NH4)2SO4. Influence of ...

Kinetic study of the cobalt electrodeposition onto glassy carbon electrode from ammonium sulfate sol...

Synthesis of Zn compounds derived from 1H-benzimidazol-2-ylmethanamine

ELECTROCHEMICAL STUDY ABOUT ZINC ELECTRODEPOSITION ONTO GCE AND HOPG SUBSTRATES