2011
Morales-Ríos Martha S., López-Camacho Perla Y., Jacobo-Cabral Carlos O., Pérez-Rojas Nadia A., Trujillo-Serrato Joel J., Burgueño-Tapia Eleuterio, Súarez-Castillo Oscar R., Joseph-Nathan Pedro. Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase.J. Mass. Spectrom. 46, 489495 (2011). DOI 10.1002/jms.1915.
Abstract
Gas phase skeletal rearrangements of regioisomeric 3-cyano-2-methoxy-3a-alkylfuro[2,3-b]- and [3,2-b]indoles were evidenced by product ions [M ? 32]+, consistent with loss of methanol, on electron ionization in their mass spectra. The rearranged products occurring in gas phase were demonstrated to have elemental composition and fragmentation properties identical to those of authentic samples of 2-indolyl cyanomalonates. Isotopic labeling experiments support the formation mechanism of the [M ? 32]+ ion. Additional thermal gas-phase reaction products were characterized by comparison with an authentic sample.
Synthesis of Indolylindolines Mediated by tert-BuNH2
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters
Trapping enols of esters and lactones with diazomethane
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters