Producción Científica Profesorado

Diastereomeric C-glycosyloxanthrones from picramnia antidesma



Rojas Lima, Susana

1999

María del Rosario Hernández-Medel, Claudia O. Ramírez-Corzas, M. Nalleli Rivera-Domínguez, Julieta Ramírez-Mendez, Rosa L. Santillan Baca and Susana Rojas-Lima, Diastereomeric C-glycosyloxanthrones from Picramia antidesma, Phytochemistry, 50, 1379-1383 (1999). DOI: http://dx.doi.org/10.1016/S0031-9422(98)00354-9


Abstract


Nine compounds were isolated and identified from the stem of Picramnia antidesma. Two of the isolated compounds: mayoside and saroside, which is new, are diastereoisomeric oxanthrones. The structure of saroside has been obtained on the basis of spectroscopic evidence. The absolute configuration of this diastereoisomeric pair has been determined by CD spectra, and that of saroside was further established by X-ray crystallographic analysis.



Producto de Investigación




Artículos relacionados

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...

Furocoumarins of three species of the genus Dorstenia

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

The Structural Chemistry of N-Monolithium Borazines

Phenylboronic acid catalyzed-cyanide promoted, one-pot synthesis of 2-(2-hydroxyphenyl)benzoxazole d...

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

Synthesis and Study of Isomeric Benzo[1,4]oxazines and Benzothiazolines by NMR Spectroscopy and X-Ra...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...