Producción Científica Profesorado

Diastereomeric C-glycosyloxanthrones from picramnia antidesma



Rojas Lima, Susana

1999

María del Rosario Hernández-Medel, Claudia O. Ramírez-Corzas, M. Nalleli Rivera-Domínguez, Julieta Ramírez-Mendez, Rosa L. Santillan Baca and Susana Rojas-Lima, Diastereomeric C-glycosyloxanthrones from Picramia antidesma, Phytochemistry, 50, 1379-1383 (1999). DOI: http://dx.doi.org/10.1016/S0031-9422(98)00354-9


Abstract


Nine compounds were isolated and identified from the stem of Picramnia antidesma. Two of the isolated compounds: mayoside and saroside, which is new, are diastereoisomeric oxanthrones. The structure of saroside has been obtained on the basis of spectroscopic evidence. The absolute configuration of this diastereoisomeric pair has been determined by CD spectra, and that of saroside was further established by X-ray crystallographic analysis.



Producto de Investigación




Artículos relacionados

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Synthesis and Study of Monomeric and Dimeric Boronates by Spectroscopic Methods and X-ray Crystallog...

Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...

The Structural Chemistry of N-Monolithium Borazines

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

A practical access to acyl radicals from acyl hydrazides

O-benzyl-N-(2-furoyl)thiocarbamate

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...