Producción Científica Profesorado

Diastereomeric C-glycosyloxanthrones from picramnia antidesma



Rojas Lima, Susana

1999

María del Rosario Hernández-Medel, Claudia O. Ramírez-Corzas, M. Nalleli Rivera-Domínguez, Julieta Ramírez-Mendez, Rosa L. Santillan Baca and Susana Rojas-Lima, Diastereomeric C-glycosyloxanthrones from Picramia antidesma, Phytochemistry, 50, 1379-1383 (1999). DOI: http://dx.doi.org/10.1016/S0031-9422(98)00354-9


Abstract


Nine compounds were isolated and identified from the stem of Picramnia antidesma. Two of the isolated compounds: mayoside and saroside, which is new, are diastereoisomeric oxanthrones. The structure of saroside has been obtained on the basis of spectroscopic evidence. The absolute configuration of this diastereoisomeric pair has been determined by CD spectra, and that of saroside was further established by X-ray crystallographic analysis.



Producto de Investigación




Artículos relacionados

Comparative Structural Characterization of the Biquaternized N-CH3 and N-BH3 Derivatives of the cis-...

Structural studies of spiroarsoranes derived from 2-aminophenols

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

Enantioselective synthesis of ?-amino acids. Part 10: Preparation of novel ?,?- and ?,?-disubstitute...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

Ylidaddukte der Penteltrichloride

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...