2008
Hydrogen bond studies in substituted N-(2-hydroxyphenyl)-2-[(4-methylbenzenesulfonyl)amino]acetamides. Liliana Aguilar-Castro, Margarita Tlahuextl, Luis H. Mendoza-Huizar, Antonio R. Tapia-Benavides, and Hugo Tlahuext. Arkivoc. 2008. ISSN: 1424-6369
Abstract
Six substituted N-(2-hydroxyphenyl)-2-[(4-methylbenzensulfonyl)amino]acetamides 7-12 have been synthesized from 2-amino-3-nitrophenol, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 2-amino-4-chlorophenol, 2-amino-4-tert-butylphenol, 2-amino-4-chloro-5-nitrophenol, and the [(4-methylbenzenesulfonyl)amino]acetyl chloride derivative of [(4-methylbenzenesulfonyl)amino]acetic acid. These compounds have been characterized by FAB mass spectrometry, IR, and NMR (1H, 13C, 15N) spectroscopy. Variable temperature NMR experiments on compounds 7-12 gave evidence for the formation of intra- and intermolecular hydrogen-bonds in solution. The molecular structure of 7 and 12 was determined by X-ray crystallography. The electronic behavior of the intramolecular hydrogen-bonds in these compounds was established by NBO studies.
Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?
Underpotential deposition of cobalt onto polycrystalline platinum
Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane
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