2008
Noemí Andrade-López, José G. Alvarado-Rodríguez, Simplicio González-Montiel, Elena Páez-Hernández, Carlos Andrés Galán-Vidal, Araceli Jiménez-Pérez. Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands. ARKIVOC (2008) v 43-54. ISSN 1424-6376.
Abstract
Coordinative behavior of the di-(2-pyridyl)hydroxymethane (1) and di-(2-pyridyl)-2- pyridylsulfanylmethane (2) ligands towards Pd(II) and Pt(II) is described. The compounds 3-5 were characterized by IR, mass spectrometry and NMR spectroscopy. Crystal structures of [Pt{(C5H4N)2CH(OH)}Cl2] 3 and [Pd{(C5H4N)2CH(2-C5H4NS)}Cl2] 4 as DMSO solvates displayed the formation of neutral mononuclear complexes. In the complexes 3 and 4 is observed the formation of six-membered chelate rings. The local geometry of the metallic atoms can be described as square planar in the title complexes.
Synthesis, Characterization and Catalytic Activity of Supported NiMo Catalysts
ELECTROCHEMICAL STUDY ABOUT ZINC ELECTRODEPOSITION ONTO GCE AND HOPG SUBSTRATES
Revisión de variables de diseño y condiciones de operación en la electrocoagulación